Bicyclic guanidinate compounds of magnesium and their activity as pre-catalysts in the Tishchenko reaction.
نویسندگان
چکیده
A synthetic route to magnesium guanidinate compounds that avoids ligand redistribution is reported; selected derivatives are active pre-catalysts in the dimerization of aldehydes.
منابع مشابه
Bicyclic-guanidines, -guanidinates and -guanidinium salts: wide ranging applications from a simple family of molecules.
Bicyclic guanidines have physical, electronic and chemical properties that differentiate them from their acyclic counterparts, with many of these characteristics directly imposed by the rigid framework. These distinctive features have led to this class of molecule finding practical applications in many areas of chemistry, including organocatalysis and as ligands in coordination compounds. In ad...
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 17 شماره
صفحات -
تاریخ انتشار 2011